The Top 10 Brunettes in Hollywood. Sophisticated, moody, mysterious, intelligent--the right shade of brown gives these leading ladies all kinds of depth. Sofia Vergara Vergara's natural shade is much lighter than the sultry espresso she's now known for. George Papanikolas, who worked on the Modern Family star's tresses leading up to the Golden Globes, says the look is fairly easy to duplicate. "If the client doesn't have any gray, start with a demi-permanent color that has no ammonia and delivers exceptional shine in a medium neutral or golden brown base, with light and medium golden brown lowlights, then gloss all the hair in a dark golden blond." Anne Hathaway Hathaway's russet-flecked auburn is the work of Hollywood colorist Marie Robinson. "Color hair with a semi-permanent in medium rich brown with slight warm tones to give it shine," Robinson advises. "Then add random golden highlights on the crown and around the face to give it some po...